For some reason, this job doesn't match, and condor_q -better-analyze isn't too helpful.  By changing the requirements to
 
 {code}
-requirements = debug(PSYS == "LINUX" && ARCH == "X86_64" && DaemonStartTime > 100)
+requirements = debug(OPSYS == "LINUX" && ARCH == "X86_64" && DaemonStartTime > 100)
 {endcode}
 
 And adding D_FULLDEBUG to the startd, the startd log shows: